Calcium was named
after the Latin term calx meaning lime, and is a reactive silvery metallic
element found in Group 2 of the periodic table. It was first isolated in 1808
in England when Sir Humphry Davy electrolyzed a mixture of lime and mercuric
oxide.
calcium is
in fact classed as a minor metal. Say ‘calcium’ and a metallic substance does
not immediately spring to mind, rather a chalky powdery rock or possibly a
bottle of milk.
Calcium is,
however, a metal in its pure form, though rarely seen in this state due to its
instability. In air, calcium decomposes rapidly into calcium hydroxide and
calcium carbonate.
Although
calcium is the fifth most abundant element (and 3rd most abundant metal) in the
earth’s crust, present at a level of about 3% in the oceans and soil, it is
never found free in nature. Calcium easily forms compounds by reacting with not
only air but also with water and acid (on contact with water or acid, hydrogen
gas is made in a fairly controlled manner, in comparison to the other alkali
metals).
Today metallic
calcium is obtained through the electrolysis of a fused salt such as calcium
chloride. Once exposed to air, elemental calcium rapidly forms a grey-white
oxide and nitride coating. Unlike magnesium, calcium is quite difficult to
ignite, but once lit, it burns with a brilliant high-intensity red flame. Also,
calcium metal is obtained by the Aluminothermic process of metallic aluminum to
reduce lime under vacuum and high temperature, and then distillation to obtain
calcium which is mainstream method currently.
Due to its high reactivity with common materials, there is
very little demand for metallic calcium.
Calcium metal is used as a reducing agent in
preparing other metals such as thorium and uranium. It is also used as an
alloying agent for aluminium, beryllium, copper, lead and magnesium alloys.
In modern industry, calcium metal is used as:
•a reducing agent in preparing other metals such as chromium, thorium and uranium, rare
earth, zirconium, as well as magnetic materials such as Sm-Co alloys,
hydrogen absorbing materials such as lanthanum-nickel alloys and
titanium-nickel alloys.
•Alloying agent: It is also used as an alloying agent for
aluminum, beryllium, copper, lead and magnesium alloys. Lead-calcium alloy
containing 0.04% calcium has high hardness and corrosion resistance, and is
used as the outer skin of cable and battery lead plate; calcium is added to
aluminum alloy to enhance plasticity.
•Desulfurization and decarburization agent: for steel & iron and iron
alloy industry widely.•Deoxidizer: when smelting tin bronze, nickel, steel, calcium
is used as a deoxidizer.
Absorbent: Calcium is used as an absorbent in the production
of electronic tubes.